I just got done tune a 32/36. When i first put mine on my '88 sammy i had almost the same issue. If it's a new carb check the primary idle jet if that is too big it will flood out or run really rich. I'm running a "40" and it runs great. Check the posting "need help with Weber 32/36" back on 12.25.07 at 5:30 ish.
Plus like what was said above, make sure that base plates not leaking and that you don't have a vac line hooked up to the vent on the fuel bowl, it looks like something goes there but it does not, if you do then it will do the same thing, flood out and/or run like crap.