Total nonsense, IMHO.
How rust works: science.howstuffworks.com/question445.htm
Not sure about Zuki's, but many cars have used the body/frame as a ground (current flowing). Electrons didn't build up in the metal... or if they do, it didn't stop my cars from rusting out. Oh, and if I hooked 400V up to the body, what would that do to my electronics?
The way to "prevent" rust is to avoid moisture from collecting directly against metal (paint, undercoating, galvenizing) and minimize exposure time (wash out mud, leaves... and allow for water drainage.)
The only semi-effective system I saw was one used by the utility... in MD, if I recall. Each time a truck rolled in, it'd pass over pressure nozzles in the shop floor, washing the vehicle's underside. They said they had fewer cases of rust, until they went with Chevy trucks. (70's Chevy trucks would catch crud *behind* the fenderwells.)