for 4x4's and passenger cars nitrogen filled tires are of no use. for race car tires nitrogen maintains tire pressure, by not expanding when heated. regular compressed air is all you need.
nitrogen is chemicaly inert, and displaces oxygen.
carbon dioxide will change tires pressure during temerature changes, also when co2 is mixed with moisture it forms carbolic acid. if someone were to only use co2 in there tires over a period of time carbolic acids would form, and deteriate the rubber of the tires, and steel rims would rust on the inside. for in the field quick tire fills, and to operate power tools co2 works great, but you should replace co2 filled tires with compressed air afterwards.