Yes your rims should be 6 inch rims on a 2004 ZR2. Those are really nice rims by the way and they would hold 235/75, 235/70 series and 30/9.5015 tires just fine. I have 235/75 on one of my trucks and 235/70s on another BUT I have the stock 5.5 inch rims on both my trucks. One has coil lifts the other OME springs. The 235/70s run fine but I can tell you from experience I slid it on the interstate last year and went down into the median and both of the rims on the side of the direction of the slide got mud and grass pressure packed into the rim and tire seat area. One tire lost some air in the process. Took it to my tire dealer, had them pull the tires, clean the beads and rims and re-mount = no problems.
On 5.5 inch rims, 70 series is as wide as I am comfortable with. I am going to try some 30/9.50/15s though. With 6 inch rims you shouldn't have a problem fitting them on your truck. As snow said, the 235/75 series will rub your frame a little on full lock, but depending on how aggressive the tread is on your tires, it really is not significant. Even with the fender molding on your ZR2, I'm thinking you could get away with a 30/9.50/15 size tire with some coil spacers OR a set of OME springs. These typically run from about 29.7 inches to a full 30 inches in diameter. That's as large a diameter as you'll fit on your truck without some significant rubbing.
IF you are ready to bust for some big bucks on tires, you might consider going to your tire dealership, tell them what you need ask him to mount a 235/75 or 30/9.50 and have them mount it on the front and check out the clearnce. I too have had the thought of switching to 16" rims for more tire choices... but I have resisted the urge. The Sidekick Sport models had 16 inch wheels and the aluminum ones were very nice looking. GVs have 16 inch wheels as well.